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Heat Transfer

#heat-transfer
1.0

Equations

Rate of heat transfer by conduction

In notes →
Q^=−kAdTdy=−kAT2−T1y\hat{Q} = -kA\frac{dT}{dy} = -kA\frac{T_2 - T_1}{y}
  • Q^\hat{Q} — rate of heat transfer (thermal energy crossing area AA per unit time), in watts (W\text{W})
  • kk — thermal conductivity of the wall, in watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K}))
  • AA — area perpendicular to heat transfer, in square metres (m2\text{m}^2)
  • dT/dydT/dy — temperature gradient, in kelvin per metre (K/m\text{K/m})
  • T2,T1T_2, T_1 — temperatures either side of the wall, in kelvin (K\text{K})
  • yy — distance component of thickness, in metres (m\text{m})

Rate of heat transfer by convection

In notes →
Q^=hAΔT\hat{Q} = hA \Delta T
  • Q^\hat{Q} — rate of heat transfer (thermal energy crossing area AA per unit time), in watts (W\text{W})
  • hh — individual (film) heat transfer coefficient — how readily heat crosses between the bulk fluid and the wall by convection, in watts per square metre-kelvin (W/(m2⋅K)\text{W}/(\text{m}^2 \cdot \text{K}))
  • AA — area, in square metres (m2\text{m}^2)
  • ΔT\Delta T — temperature gradient, in kelvin (K\text{K})

Nusselt number

In notes →
Nu=hDkfbNu = \frac{hD}{k_{fb}}
  • NuNu — Nusselt number (ratio of convective to conductive heat transfer), dimensionless
  • hh — individual heat transfer coefficient, in watts per square metre-kelvin (W/(m2⋅K)\text{W}/(\text{m}^2 \cdot \text{K}))
  • DD — diameter of the pipe or tank, or characteristic length of the pipe, in metres (m\text{m})
  • kfbk_{fb} — thermal conductivity of the bulk fluid, in watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K}))

Prandtl number

In notes →
Pr=CpμbkfbPr = \frac{C_p \mu_b}{k_{fb}}
  • PrPr — Prandtl number (ratio of molecular momentum to thermal diffusivity), dimensionless
  • CpC_p — heat capacity, in joules per kilogram-kelvin (J/(kg⋅K)\text{J}/(\text{kg} \cdot \text{K}))
  • μb\mu_b — viscosity of the bulk fluid, in pascal-seconds (Pa⋅s\text{Pa} \cdot \text{s})
  • kfbk_{fb} — thermal conductivity of the bulk fluid, in watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K}))

Conductive resistance of a wall

In notes →
Rcond=xkR_{cond} = \frac{x}{k}
  • RcondR_{cond} — conductive thermal resistance per unit area, in square metre-kelvin per watt (m2⋅K/W\text{m}^2 \cdot \text{K}/\text{W})
  • xx — thickness of the layer, in metres (m\text{m})
  • kk — thermal conductivity of the layer's material, in watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K}))

Conductive resistance of a wall

In notes →
Rtotal=∑ixikiR_{total} = \sum_i \frac{x_i}{k_i}
  • RtotalR_{total} — total conductive resistance of the composite wall per unit area, in square metre-kelvin per watt (m2⋅K/W\text{m}^2 \cdot \text{K}/\text{W})
  • xi,kix_i, k_i — thickness and thermal conductivity of layer ii, in metres (m\text{m}) and watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K})) respectively

Rate of heat transfer using U

In notes →
Q^=UAΔTLMTD\hat{Q} = UA \Delta T_{LMTD}
  • Q^\hat{Q} — rate of heat transfer (thermal energy crossing area AA per unit time), in watts (W\text{W})
  • UU — overall heat transfer coefficient (lumps both film coefficients and the wall's own conduction resistance into one number, avoiding the need to measure ΔT\Delta T at each internal interface), in watts per square metre-kelvin (W/(m2⋅K)\text{W}/(\text{m}^2 \cdot \text{K}))
  • AA — area, in square metres (m2\text{m}^2)
  • ΔTLMTD\Delta T_{LMTD} — logarithmic mean temperature difference, in kelvin (K\text{K})

Overall heat transfer coefficient from film coefficients

In notes →
1U=1h1+xk+1h2+Rf\frac{1}{U} = \frac{1}{h_1} + \frac{x}{k} + \frac{1}{h_2} + R_f
  • UU — overall heat transfer coefficient (lumps both film coefficients and the wall's own conduction resistance into one number), in watts per square metre-kelvin (W/(m2⋅K)\text{W}/(\text{m}^2 \cdot \text{K}))
  • h1,h2h_1, h_2 — individual film heat transfer coefficients on either side of the wall, in watts per square metre-kelvin (W/(m2⋅K)\text{W}/(\text{m}^2 \cdot \text{K}))
  • xx — thickness of the wall, in metres (m\text{m})
  • kk — thermal conductivity of the wall, in watts per metre-kelvin (W/(m⋅K)\text{W}/(\text{m} \cdot \text{K}))
  • RfR_f — fouling resistance at a film surface (e.g. microbial biofilm or scale buildup), in square metre-kelvin per watt (m2⋅K/W\text{m}^2 \cdot \text{K}/\text{W})

Logarithmic mean temperature difference (LMTD)

In notes →
ΔTLMTD=ΔT2−ΔT1ln⁡(ΔT2/ΔT1)\Delta T_{LMTD} = \frac{\Delta T_2 - \Delta T_1}{\ln(\Delta T_2 / \Delta T_1)}
  • ΔTLMTD\Delta T_{LMTD} — logarithmic mean temperature difference (single equivalent driving-force temperature for the whole exchanger, replacing the ΔT\Delta T that actually varies along its length), in kelvin (K\text{K})
  • ΔT2,ΔT1\Delta T_2, \Delta T_1 — temperature differences at the two ends of the heat exchanger, in kelvin (K\text{K})

Metabolic heat from oxygen consumption (Cooney's correlation)

In notes →
Qmetabolic=ΔHO2×nO2Q_{metabolic} = \Delta H_{O_2} \times n_{O_2}
  • QmetabolicQ_{metabolic} — metabolic heat released by aerobic respiration, in kilojoules (kJ\text{kJ})
  • ΔHO2\Delta H_{O_2} — heat released per mole of oxygen consumed (**Cooney's correlation**), approximately 460 kJ/mol460\,\text{kJ/mol} (≈14 kJ/g\approx 14\,\text{kJ/g} O2O_2, since 460/32≈14.4460/32 \approx 14.4)
  • nO2n_{O_2} — moles of oxygen consumed by the culture (mol\text{mol})

Scale-up heat transfer challenge

In notes →
AV∝D2D3=1D\frac{A}{V} \propto \frac{D^2}{D^3} = \frac{1}{D}
  • AA — cooling surface area available (jacket or coil), in square metres (m2\text{m}^2)
  • VV — reactor working volume, in cubic metres (m3\text{m}^3)
  • DD — characteristic vessel diameter, in metres (m\text{m})
11 formulas